穐田・吉沢研究室（錯体化学・超分子化学）

東京工業大学科学技術創成研究院化学生命科学研究所		物質理工学院応用化学系（応用化学コース）

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２００８～２０１９年
	M. Yoshizawa,* L. Catti Bent Anthracene Dimers as Versatile Building Blocks for Supramolecular Capsules Acc. Chem. Res., 2019, 52, 2392-2404 (DOI: 10.1021/acs.accounts.9b00301). Y. Satoh, L. Catti, M. Akita, M. Yoshizawa* A Redox-Active Heterocyclic Capsule: Radical Generation, Oxygenation, and Guest Uptake/Release J. Am. Chem. Soc., 2019, 141, 12268-12273 (DOI: 10.1021/jacs.9b03419). K. Matsumoto, S. Kusaba, Y. Tanaka, Y. Sei, M. Akita, K. Aritani, M. Haga, M. Yoshizawa* A Peanut-Shaped Polyaromatic Capsule: Solvent-Dependent Transformation and Electronic Properties of a Non-Contacted Fullerene Dimer Angew. Chem. Int. Ed., 2019, 58, 8463-8467 (DOI: 10.1002/anie.201903117). L. Catti, N. Kishida, T. Kai, M. Akita, M. Yoshizawa* Polyaromatic Nanocapsules as Photoresponsive Hosts in Water Nature Commun., 2019, 10, 1948 (DOI: 10.1038/s41467-019-09928-x). OPEN T. Nishioka, K. Kuroda, M. Akita, M. Yoshizawa* A Polyaromatic Gemini Amphiphile That Assembles into a Well-defined Aromatic Micelle with Higher Stability and Host Functions Angew. Chem. Int. Ed., 2019, 58, 6579-6583 (DOI: 10.1002/anie.201814624). M. Yamashina, T. Tsutsui, Y. Sei, M. Akita, M. Yoshizawa* A Polyaromatic Receptor with High Androgen Affinity Science Adv., 2019, 5, eaav3179 (DOI: 10.1126/sciadv.aav3179). OPEN T. Tsutsui, S. Kusaba, M. Yamashina, M. Akita, M. Yoshizawa* Open versus Closed Polyaromatic Nanocavity: Enhanced Host Abilities for Large Dyes and Pigments Chem. Eur. J., 2019, 25, 4320-4324 (DOI: 10.1002/chem.201806409). F. Lu, K. Hagiwara, M. Yoshizawa, K. Nagura, S. Ishihara, T. Nakanishi* Luminescence Tuning with Excellent Colour Homogeneity and Steadiness Using Fluorescent Molecular Liquids J. Mater. Chem. C, 2019, 7, 2577-2582 (DOI: 10.1039/C8TC06254D). K. Kuroda, K. Yazaki, Y. Tanaka, M. Akita, H. Sakai,* T. Hasobe, N. V. Tkachenko, M. Yoshizawa* A Pentacene-based Nanotube Displaying Enriched Electrochemical and Photochemical Activity Angew. Chem. Int. Ed., 2019, 58, 1115-1119 (DOI: 10.1002/anie.201812976). 二木啓太・吉沢道人* 自己組織化カプセルによる生体分子の精密識別化学工業, 2019, 11, 21-27. 岸田夏月・吉沢道人* 光スイッチをもつ分子カプセル ─分子の内包と放出ができる“賢いナノ道具” 化学, 2019, 74, 38-42. 　- - - - - - - - - - - - - - - - S. Origuchi, M. Kishimoto, M. Yoshizawa, S. Yoshimoto* A Supramolecular Approach to Preparation of Nanographene Adlayers Using Water-soluble Molecular Capsules Angew. Chem. Int. Ed., 2018, 57, 15481-15485 (DOI: 10.1002/anie.201809258). M. Yamashina, S. Kusaba, M. Akita, T. Kikuchi, M. Yoshizawa* Cramming versus Threading of Long Amphiphilic Oligomers into a Polyaromatic Capsule Nature Commun., 2018, 9, 4227 (DOI: 10.1038/s41467-018-06458-w). OPEN F. Lu, K. Jang, I. Osica, K. Hagiwara, M. Yoshizawa, M. Ishii, Y. Chino, K. Ohta, K. Ludwichowska, K. J. Kurzydlowski, S. Ishihara, T. Nakanishi* Supercooling of Functional Alkyl-π Molecular Liquids Chem. Sci., 2018, 9, 6774-6778 (DOI: 10.1039/C8SC02723D). K. Yazaki, L. Catti, M. Yoshizawa* Polyaromatic Molecular Tubes: from Strategic Synthesis to Host Functions Chem. Commun., 2018, 54, 3195-3206 (DOI: 10.1039/C8CC00799C) (feature article). S. Kusaba, M. Yamashina, M. Akita, T. Kikuchi, M. Yoshizawa* Hydrophilic Oligo(Lactic Acid)s Captured by a Hydrophobic Polyaromatic Cavity in Water Angew. Chem. Int. Ed., 2018, 57, 3706-3710 (DOI: 10.1002/anie.201800432). K. Kuroda, M. Otsuki, K. Yazaki, Y. Sei, M. Akita, M. Yoshizawa* Alkylation, Heating, and Doping-Induced Emission Enhancement of a Polyaromatic Tube in the Solid State Chem. Asian J., 2018, 13, 515-519 (DOI: 10.1002/asia.201800034). T. Kai, M. Kishimoto, M. Akita, M. Yoshizawa* Encapsulation-Induced Emission Enhancement (EIEE) of Eu(III)-Complexes by Aromatic Micelles in Water Chem. Commun., 2018, 54, 956-959 (DOI: 10.1039/C7CC09450G). S. Kai, M. Nakagawa, T. Kojima, X. Li, M. Yamashina, M. Yoshizawa, S. Hiraoka* Self‐Assembly Process of a Pd2L4 Capsule: Steric Interactions between Neighboring Components Favor the Formation of Large Intermediates Chem. Eur. J., 2018, 24, 3965-3969 (DOI: 10.1002/chem.201705253). 矢崎晃平・吉沢道人* 新しい分子集合体の開発：2 つの空間を持つナノ構造体の合成と性質月刊マテリアルステージ, 2018, 18. 56-61 山科雅裕・吉沢道人* 分子カプセルを活用した水中での糖分子の識別月刊バイオインダストリー, 2018, 3, 47-55. 　- - - - - - - - - - - - - - - - S. Matsuno, M. Yamashina, Y. Sei, M. Akita, A. Kuzume, K. Yamamoto, M. Yoshizawa* Exact Mass Analysis of Sulfur Clusters upon Encapsulation by a Polyaromatic Capsular Matrix Nature Commun., 2017, 8, 749 (DOI: 10.1038/s41467-017-00605-5). OPEN A. Matsumoto, K. Jono, M. Akita, M. Yoshizawa* Side-Chain-Directed Dispersion of MoS2 Nanosheets by V-Shaped Polyaromatic Compounds Chem. Asian J., 2017,12, 2889-2893 (DOI: 10.1002/asia.201701199R1). M. Yamashina, M. Akita, T. Hasegawa, S. Hayashi, M. Yoshizawa* A Polyaromatic Nanocapsule as a Sucrose Receptor in Water Science Adv., 2017, 3, e1701126 (DOI: 10.1126/sciadv.1701126). OPEN K. Kondo, J. K. Klosterman, M. Yoshizawa* Aromatic Micelles as a New Class of Aqueous Molecular Flasks Chem. Eur. J., 2017, 23, 16710-16721 (DOI: 10.1002/chem.201702519) (Minireview). S. Prusty, K. Yazaki, M. Yoshizawa, D. K. Chand* A Truncated Molecular Star Chem. Eur. J., 2017, 23, 12456-12461 (DOI: 10.1002/chem.201702264).. K. Kurihara, K. Yazaki, M. Akita, M. Yoshizawa* A Switchable Open/closed Polyaromatic Macrocycle that Shows Reversible Binding of Long Hydrophilic Molecules Angew. Chem. Int. Ed., 2017, 56, 11360-11364 (DOI: 10.1002/anie.201703357). K. Yazaki, M. Akita, S. Prusty, D. K. Chand, T. Kikuchi, H. Sato, M. Yoshizawa* Polyaromatic Molecular Peanuts Nature Commun., 2017, 8, 15914 (DOI: 10.1038/ncomms15914). OPEN K. Jono, A. Suzuki, M. Akita, K. Albrecht, K. Yamamoto, M. Yoshizawa* A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds Angew. Chem. Int. Ed., 2017, 56, 3570-3574 (DOI: 10.1002/anie.201612489). M. Kishimoto, K. Kondo, M. Akita, M. Yoshizawa* A pH-Responsive Molecular Capsule with an Acridine Shell: Catch and Release of Large Hydrophobic Compounds Chem. Commun., 2017, 53, 1425-1428 (DOI: 10.1039/C6CC09094J). M. M. Sartin, K. Kondo, M. Yoshizawa, S. Takeuchi, T. Tahara* Local Environment inside a Novel Aromatic Micelle Investigated by Steady-state and Femtosecond Fluorescence Spectroscopy of an Encapsulated Solvatochromic Probe Phys. Chem. Chem. Phys., 2017, 19, 757-765 (DOI: 10.1039/C6CP06174E). M. Yoshizawa,* M. Yamashina Coordination-Driven Nanostructures with Polyaromatic Shells Chem. Lett., 2017, 46, 163-171 (DOI: 10.1246/cl.160852) (Highlight Review). OPEN 松野匠・吉沢道人* 人工ナノカプセルによるカフェインの高選択的内包化学と生物, 2017, 55, 158-160. 　- - - - - - - - - - - - - - - - K. Yazaki, S. Noda, Y. Tanaka, Y. Sei, M. Akita, M. Yoshizawa* An M2L4 Molecular Capsule with a Redox Switchable Polyradical Shell Angew. Chem. Int. Ed., 2016, 55, 15031-15034 (DOI: 10.1002/anie.201608350). I. Jeon, S. Zeljkovic, K. Kondo, M. Yoshizawa, Y. Matsuo* Interface Engineering of Metal Oxides using Ammonium Anthracene in Inverted Organic Solar Cells ACS Appl. Mater. Interfaces, 2016, 8, 29866-29871 (DOI: 10.1021/acsami.6b09684). K. Yazaki, Y. Sei, M. Akita, M. Yoshizawa* Polycationic-Shelled Capsular and Tubular Nanostructures and Their Anionic-Guest Binding Properties Chem. Eur. J., 2016, 22, 17557-17561 (DOI: 10.1002/chem.201604384). M. Yamashina, S. Matsuno, Y. Sei, M. Akita, M. Yoshizawa* Recognition of Multiple Methyl Groups on Aromatic Rings by a Polyaromatic Cavity Chem. Eur. J., 2016, 22, 14147-14150 (DOI: 10.1002/chem.201603032). A. Suzuki, M. Akita, M. Yoshizawa* Amphiphilic Tribranched Scaffolds with Polyaromatic Panels That Wrap Perylene Stacks Displaying Unusual Emissions Chem. Commun., 2016, 52, 10024-10027 (DOI: 10.1039/C6CC04823D). A. Ahmedova,* R. Mihaylova, D. Momekova, P. Shestakova, S. Stoykova, J. Zaharieva, M. Yamashina, G. Momekov, M. Akita, M. Yoshizawa M2L4 Coordination Capsules with Tunable Anticancer Activity upon Guest Encapsulation Dalton Trans., 2016, 45, 13214-13221 (DOI: 10.1039/C6DT01801G) (Special Issue on Metallodrugs). S. Sekiguchi, K. Kondo, Y. Sei, M. Akita, M. Yoshizawa* Engineering Stacks of V-Shaped Polyaromatic Compounds with Alkyl Chains for Enhanced Emission in the Solid State Angew. Chem. Int. Ed., 2016, 55, 6906-6910 (DOI: 10.1002/anie.201602502). A. Suzuki, K. Kondo, Y. Sei, M. Akita, M. Yoshizawa* A Fluorescent Molecular Capsule with a Flexible Polyaromatic Shell for Detecting Monoterpene Compounds in Water Chem. Commun., 2016, 52, 3151-3154 (DOI: 10.1039/C5CC09647B). T. Omagari, A. Suzuki, M. Akita, M. Yoshizawa* Efficient Catalytic Epoxidation in Water by Axial N-Ligand-Free Mn-Porphyrins within a Micellar Capsule J. Am. Chem. Soc., 2016, 138, 499-502 (DOI: 10.1021/jacs.5b11665). K. Kondo, M. Akita, M. Yoshizawa* Solubility Switching of Metallo-Phthalocyanines and Their Larger Derivatives upon Encapsulation Chem. Eur. J., 2016, 22, 1937-1940 (DOI: 10.1002/chem.201505036). A. Ahmedova,* D. Momekova, M. Yamashina, P. Shestakova, G. Momekov, M. Akita, M. Yoshizawa* Anticancer Potencies of Pt(II)- and Pd(II)-linked M2L4 Coordination Capsules with Improved Selectivity Chem. Asian J., 2016, 11, 474-477 (DOI: 10.1002/asia.201501238). 吉沢道人・岸本真依・近藤圭・穐田宗隆 pH応答性分子カプセル、疎水性化合物の可溶化剤、及び疎水性化合物の可溶化方法（特許出願）特願2016-033452, 2016年2月24日（出願人東京工業大学）　- - - - - - - - - - - - - - - - M. Yamashina, M. Sartin, Y. Sei, M. Akita, S. Takeuchi, T. Tahara, M. Yoshizawa Preparation of Highly Fluorescent Host-Guest Complexes with Tunable Color upon Encapsulation J. Am. Chem. Soc., 2015, 137, 9266-9269 (DOI: 10.1021/jacs.5b06195). Y. Okazawa, K. Kondo, M. Akita, M. Yoshizawa* Well-defined Aqueous Nanoassemblies from Amphiphilic meta-Terphenyls and Their Guest Incorporation Chem. Sci., 2015, 6, 5059-5062 (DOI: 10.1039/C5SC01545F). OPEN K. Kondo, M. Akita, T. Nakagawa, Y. Matsuo, M. Yoshizawa* A V-Shaped Polyaromatic Amphiphile: Solubilization of Various Nanocarbons in Water and Enhanced Photostability Chem. Eur. J., 2015, 21, 12741-12746 (DOI: 10.1002/chem.201501414). K. Hagiwara, M. Otsuki, M. Akita, M. Yoshizawa* Polyaromatic Molecular Tubes with a Subnanometer Pore and the Guest-Induced Emission Enhancement Behavior Chem. Commun., 2015, 51, 10451-10454 (DOI: 10.1039/C5CC02931G). M. Yamashina, T. Yuki, Y. Sei, M. Akita, M. Yoshizawa* Anisotropic Expansion of an M2L4 Coordination Capsule: Host Capability and Frame Rearrangement Chem. Eur. J., 2015, 21, 4200-4204 (DOI: 10.1002/chem.201406445). Y. Okazawa, K. Kondo, M. Akita, M. Yoshizawa* Polyaromatic Nanocapsules Displaying Aggregation-Induced Enhanced Emissions in Water J. Am. Chem. Soc., 2015, 137, 98-101 (DOI: 10.1021/ja511463k). K. Hagiwara, M. Akita, M. Yoshizawa* An Aqueous Molecular Tube with Polyaromatic Frameworks Capable of Binding Fluorescent Dyes Chem. Sci., 2015, 6, 259-263 (DOI: 10.1039/C4SC02377C). OPEN 新井隆之・吉沢道人・近藤圭分散液及びその製造方法並びに膜及びその製造方法（特許出願）特願2015-0158, 2015年11月25日（出願人 JSR・東京工業大学）近藤圭・岡澤佑允・吉沢道人アントラセンを活用した分子集合体の新展開液晶, 2015, 19, 182-191. 山科雅裕・吉沢道人* ラジカル開始剤のカプセル化＝耐光性および耐熱性の向上＝光アライアンス, 2015, 6, 1-4. 　- - - - - - - - - - - - - - - - K. Yazaki, Y. Sei, M. Akita, M. Yoshizawa* A Polyaromatic Molecular Tube That Binds Long Hydrocarbons with High Selectivity Nature Commun., 2014, 5, 5179 (DOI: 10.1038/ncomms6179). OPEN K. Kondo, A. Suzuki, M. Akita, M. Yoshizawa* Micellar Polyaromatic Capsules: Enhanced Emissive Properties through Shell-Functionalization Eur. J. Org. Chem., 2014, 33, 7389-7394 (DOI: 10.1002/ejoc.201403136). M. Yamashina, Y. Sei, M. Akita, M. Yoshizawa* Safe Storage of Radical Initiators within a Polyaromatic Nanocapsule Nature Commun., 2014, 5, 4662 (DOI: 10.1038/ncomms5662). OPEN N. Kishi, M. Akita, M. Yoshizawa* Selective Host-Guest Interactions of a Transformable Coordination Capsule/Tube with Fullerenes Angew. Chem. Int. Ed., 2014, 53, 3604-3607 (DOI: 10.1002/anie.201311251). Z. Li, Y. Sei, M. Akita, M. Yoshizawa* A Solvato-Fluorochromic Macrocycle of Multiple Anthracene Fluorophores in Close Proximity Chem. Asian J., 2014, 9, 1016-1019 (DOI: 10.1002/asia.201301648). M. Yoshizawa,* J. K. Klosterman Molecular Architectures of Multi-Anthracene Assemblies Chem. Soc. Rev., 2014, 43, 1885-1898 (DOI:10.1039/C3CS60315F). 鈴木輝・吉沢道人*　芳香環の殻を持つナノカプセルの作製と蛍光特性マイクロ／ナノカプセルの調製、徐放性制御と応用事例（技術情報協会）2014, 75-79. 吉沢道人・山科雅裕・穐田宗隆分子カプセル、ステロイドの水溶化方法及び水溶化ステロイド（特許出願）特願2014-088505, 2014年4月22日（出願人東京工業大学）萩原啓太・吉沢道人　アントラセン環の殻を持つ三次元ナノ構造体の創製有機合成化学会誌 2014, 72 (6月号), 692-701. 吉沢道人・神山美穂・鈴木輝・穐田宗隆フタロシアニン及びポルフィリン等の水溶化剤、水溶化体、及び水溶化方法（特許出願）特願2014-021941, 2014年2月7日（出願人東京工業大学）近藤圭・吉沢道人アントラセン環の殻をもつ“芳香環ミセル”（特集：制限空間と高分子）高分子 2014, 63 (4月号), 229-230. 　- - - - - - - - - - - - - - - - N. Kishi, M. Akita, M. Kamiya, S. Hayashi, H.-F. Hsu, M. Yoshizawa* Facile Catch and Release of Fullerenes Using a Photoresponsive Molecular Tube J. Am. Chem. Soc., 2013, 135, 12976-12979 (DOI: 10.1021/ja406893y). A. Suzuki, K. Kondo, M. Akita, M. Yoshizawa* Atroposelective Self-Assembly of a Molecular Capsule from Amphiphilic Anthracene Trimers Angew. Chem. Int. Ed., 2013, 52, 8120-8123 (DOI: 10.1002/anie.201302789). S. S. Babu, M. J. Hollamby, J. Aimi, H. Ozawa, A. Saeki, S. Seki, K. Kobayashi, K. Hagiwara, M. Yoshizawa, H. Moehwald, T. Nakanishi* Nonvolatile Liquid Anthracenes for Facile Full-Colour Luminescence Tuning at Single Blue-Light Excitation Nature Commun., 2013, 4, 1969 (DOI: 10.1038/ncomms2969) M. Yoshizawa* Coordination Nanocages for Engineering Discrete Aromatic Stacks (Chapter 4) Metal-Molecular Assembly for Functional Materials, Springer, 2013, 29-39 (DOI: 10.1007/978-4-431-54370-1_4). N. Kishi, Z. Li, Y. Sei, M. Akita, K. Yoza, J. S. Siegel, M. Yoshizawa* Wide-Ranging Host Capability of a Pd(II)-Linked M2L4 Molecular Capsule with an Anthracene Shell Chem. Eur. J., 2013, 19, 6313-6320 (DOI: 10.1002/chem.201204010). K. Yazaki, N. Kishi, M. Akita, M. Yoshizawa* A Bowl-Shaped Organic Host Using Bispyridine Ligands: Selective Encapsulation of Carbonyl Guests in Water Chem. Commun., 2013, 49, 1630-1632 (DOI: 10.1039/C3CC38869G). K. Kondo, A. Suzuki, M. Akita, M. Yoshizawa* Micelle-like Molecular Capsules with Anthracene Shells as Photoactive Hosts Angew. Chem. Int. Ed., 2013, 52, 2308-2312 (DOI: 10.1002/anie.201208643). 李稚鴎・吉沢道人* 青色蛍光を発する分子カプセル =自己組織化を利用した三次元構造体の構築と光物性= 光アライアンス 2013, 24(3), 52-55. 　- - - - - - - - - - - - - - - - Z. Li, H. Ishizuka, Y. Sei, M. Akita, M. Yoshizawa* Extended Fluorochromism of Anthracene Trimers with a meta-Substituted Triphenylamine or Triphenylphosphine Core Chem. Asian J., 2012, 7, 1789-1794 (DOI: 10.1002/asia.201200310). Z. Li, N. Kishi, K. Yoza, M. Akita, M. Yoshizawa* Isostructural M2L4 Molecular Capsules with Anthracene Shells: Synthesis, Crystal Structures, and Fluorescent Properties Chem. Eur. J., 2012, 18, 8358-8365 (DOI: 10.1002/chem.201200155). K. Hagiwara, Y. Sei, M. Akita, M. Yoshizawa* A Tubular Macrocycle from Covalently Linked Anthracenes and meta-Phenylene Spacers Chem. Commun., 2012, 48, 7678-7680 (DOI: 10.1039/C2CC31383A). 　- - - - - - - - - - - - - - - - Z. Li, N. Kishi, K. Hasegawa, M. Akita, M. Yoshizawa* Highly Fluorescent M2L4 Molecular Capsules with Anthracene Shells Chem. Commun., 2011, 47, 8605-8607 (DOI: 10.1039/c1cc12946e). N. Kishi, Z. Li, K. Yoza, M. Akita, M. Yoshizawa* An M2L4 Molecular Capsule with an Anthracene Shell: Encapsulation of Large Guests up to 1 nm J. Am. Chem. Soc., 2011, 133, 11438-11441 (DOI: 10.1021/ja2037029). 吉沢道人・近藤圭・鈴木輝・穐田宗隆多環芳香族骨格を有する両親媒性分子の集合体およびその製造方法（特許出願）特願2011-201691,* 2011年9月15日 (出願人東京工業大学) 李稚鴎・吉沢道人* 分子カプセル ―最小の機能性カプセルを求めて― 化学と教育 2011, 59(11), 546-549. 　- - - - - - - - - - - - - - - - M. Yoshizawa,* M. Fujita* Development of Unique Chemical Phenomena within Nanometer-sized, Self-Assembled Coordination Hosts Bull. Chem. Soc. Jpn., 2010, 83, 609-618 (DOI: 10.1246/bcsj.20100035). 吉沢道人・李稚鴎・貴志礼文・穐田宗隆　発光性遷移金属錯体およびその製造方法［特許出願］特願2010-053609, 2010年3月10日 (出願人東京工業大学) 　- - - - - - - - - - - - - - - - M. Yoshizawa, J. K. Klosterman, M. Fujita Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts Angew. Chem. Int. Ed., 2009, 48, 3418-3438 (DOI: 10.1002/anie.200805340). J. Iwasa, K. Ono, M. Fujita, M. Akita, M. Yoshizawa* Switchable trans-cis Interconversion of an Amphiphilic Anthracene Trimer Chem. Commun., 2009, 5746-5748 (DOI: 10.1039/b912365b).

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